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No. You must have a paid volume license agreement. There is no free trial ISO from Microsoft (evaluation editions exist, but they expire after 90 days and are not VL).
Once you have the ISO file, you can create a bootable USB drive using tools like Rufus or the built-in Windows Disc Image burner for DVDs. Windows 10 Enterprise | Microsoft Evaluation Center
Review the Windows 10 system requirements. Register, then download and install the full-featured software for a 90-day evaluation.
Disclaimer: This article is for informational purposes only. Always consult your organization’s licensing specialist or Microsoft representative for specific compliance requirements.